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• W1541752615 abstract "Changes in the quality of green cokes available for the production of pre-baked carbon anodes used in the production of aluminum are stimulating the development of a better understanding of the thermodynamic behavior of cokes. Impurity content and crystallite sizes (over a wide range of temperature) are of particular concern. No thermodynamic model currently exists for the precise prediction of the enthalpy and entropy of cokes that can be applied to industrial processes. The present model uses a simplified structure for coke crystallites for the production of predictive calculations that can potentially incorporate the impact of various impurities. The thermodynamic properties of coke crystallites as functions of temperatures, crystallite sizes and hydrogen/sulfur contents are presented in this work. Examples of key applications of the present model are: the calculation of dehydrogenation/desulfurization curves of cokes with constrained L c and of the gaseous composition of volatile species emanating from heat treated cokes." @default.
• W1541752615 created "2016-06-24" @default.
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• W1541752615 date "2015-01-01" @default.
• W1541752615 modified "2023-09-26" @default.
• W1541752615 title "A Size-Dependent Thermodynamic Model for the Carbon/Hydrogen/Sulfur System in Coke Crystallites: Application to the Production of Pre-Baked Carbon Anodes" @default.
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• W1541752615 doi "https://doi.org/10.1007/978-3-319-48248-4_179" @default.
• W1541752615 hasPublicationYear "2015" @default.
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