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- W1541961711 abstract "It was found that the thermal decomposition of di-tert-butyl peroxalate in a solution in carbon tetrachloride is catalyzed by silochrome. Equations are proposed for homogeneous and nonhomogeneous surfaces of the catalyst, linking the effective rate constant of the decomposition of di-tert-butyl peroxalate with the rate constants of spontaneous decomposition of the peroxide, and of the catalytic decomposition in an adsorbed state. A higher correlation of the experimental data with the model of a nonhomogeneous surface of the catalyst has been established." @default.
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- W1541961711 date "1987-10-01" @default.
- W1541961711 modified "2023-09-24" @default.
- W1541961711 title "Kinetics of thermal decomposition of di-tert-butyl peroxalate in the presence of silochrome" @default.
- W1541961711 hasPublicationYear "1987" @default.
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