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- W1542088223 abstract "The separation of benzene and perdeuterobenzene by gas—liquid chromatography has been investigated on glass capillary columns. The nature of the liquid phase plays a very important role in the separation of isotopically substituted molecules, the less polar (squalene) being more effective than silicone oil. With the former, the separation is better than expected on account of the differences of vapour pressure the reverse is found with latter phase. The thermodynamic of the chromatograhic process have been studied, and the difference of ΔG, ΔH and ΔS for both substances together with the ratio of the activity coefficients on squalene and silicone oil have been calculated." @default.
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- W1542088223 date "1963-01-01" @default.
- W1542088223 modified "2023-10-15" @default.
- W1542088223 title "Isotopic effect in gas—liquid chromatography" @default.
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- W1542088223 doi "https://doi.org/10.1016/s0021-9673(01)83638-4" @default.
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