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- W1542664402 abstract "The authors present a concise discussion of heterogeneous Pd-catalyzed hydrogenation and a brief discussion of Pd-catalyzed homogeneous hydrogenation. The chapter explores the synthetic methods developed for the conjugate reduction of α, β-unsaturated carbonyl compounds focusing on those methodologies that involve the use of palladium catalysts. Three sections are considered: catalytic hydrogenation over palladium catalysts; Pd-catalyzed reductions with group 14 metal hydrides; and Pd-catalyzed reductions with other hydrogen donors. Attention is given to selective alkene and alkyne isomerization reactions of synthetic interest. A limited number of studies on the Pd-catalyzed isomerization of monoenes including its mechanistic aspects is featured. A discussion of hydrogen transfer hydrometallation promoted by Pd catalysts is included. Bis-silylation, silylboration, and borylstannation of alkynes and alkenes are reviewed. The authors explore the syn-heteropalladation of carbon–carbon unsaturated compounds with group 15, 16 and 17 heteroatom compounds." @default.
- W1542664402 created "2016-06-24" @default.
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- W1542664402 date "2005-03-02" @default.
- W1542664402 modified "2023-10-16" @default.
- W1542664402 title "Palladium-Catalyzed Homogeneous Hydrogenation: Palladium-Catalyzed Hydrogenation Equivalents" @default.
- W1542664402 doi "https://doi.org/10.1002/0471212466.ch126" @default.
- W1542664402 hasPublicationYear "2005" @default.
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