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- W1542923265 abstract "The spin Hamiltonian parameters (i.e., zero-field splittings (ZFSs) b(2)(0), b(4)(0), b(4)(4) and the g factor) for the tetragonal Gd3+ in Pr1.98Gd0.02CuO4 are studied from the superposition model and the approximation formula including admixture of the ground S-8(7/2) and the excited L-6(7/2) (L = P, D, F, G) states via the spin-orbit coupling interactions, respectively. The calculated ZFSs and g factor are in reasonable agreement with the experimental data. It is found that the impurity-ligand bonding angles related to the fourfold (C-4) axis in the impurity Gd3+ centre are about 0.71 degrees smaller than those in the host." @default.
- W1542923265 created "2016-06-24" @default.
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- W1542923265 date "2005-03-16" @default.
- W1542923265 modified "2023-10-16" @default.
- W1542923265 title "Studies of the spin Hamiltonian parameters for Gd<sup>3+</sup>in Pr<sub>1.98</sub>Gd<sub>0.02</sub>CuO<sub>4</sub>" @default.
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- W1542923265 doi "https://doi.org/10.1088/0953-2048/18/5/006" @default.
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