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• W1543000676 endingPage "2292" @default.
• W1543000676 startingPage "2284" @default.
• W1543000676 abstract "Abstract The results obtained from the Knoevenagel condensation between the aldehydes R–CHO {with R=4-MeO–C 6 H 4 , 4-NO 2 –C 6 H 4 , 4-Cl–C 6 H 4 , C 6 H 5 , 2,4,6-Me 3 –C 6 H 2 or (η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 )} and [NC–CH 2 C(O)–NH–CH(CO 2 Et)–S] 2 under different experimental conditions are reported. These studies have allowed the isolation and characterisation of three optically pure polyamides of general formula [R–CHC(CN)–C(O)–NH–CH(CO 2 Et)–CH 2 –S–] 2 with R=4-MeO–C 6 H 4 ( 3a ), 4-NO 2 –C 6 H 4 ( 3b ) or (η 5 -C 5 H 5 )Fe(η 5 -C 5 H 4 ) ( 3f ). The reactions of 3f with Na 2 [PdCl 4 ] or Pd(AcO) 2 are also studied. The treatment of Pd(AcO) 2 with 3f in a 2:1 molar ratio in refluxing toluene leads to the formation of [(η 5 -C 5 H 5 )Fe{(η 5 -C 5 H 4 )–CHC(CN)–C(O)–NH–C(CO 2 Et)CH 2 }] ( 5f ). Electrochemical studies based on cyclic voltammetry of compounds 3f and 5f are also reported." @default.
• W1543000676 created "2016-06-24" @default.
• W1543000676 creator A5000587414 @default.
• W1543000676 creator A5009312239 @default.
• W1543000676 creator A5086407689 @default.
• W1543000676 date "2004-07-01" @default.
• W1543000676 modified "2023-10-16" @default.
• W1543000676 title "Knoevenagel condensation of [NC–CH2C(O)–NH–CH(CO2Et)–S]2 with ferrocenecarbaldehyde and the activation of the σ(C–S) bond of [(η5-C5H5)Fe{(η5-C5H4)–CHC(CN)–C(O)–NH–CH(CO2Et)–CH2–S–}]2 induced by palladium(II)" @default.
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• W1543000676 doi "https://doi.org/10.1016/j.jorganchem.2004.04.008" @default.
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