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• W1543222145 abstract "It is shown that over a wide potential the impedance of the AgI/aqueous solution interface can be represented by a parallel arrangemet of a double layer capacitance C and a diffusion impedance Zw. The validity of this scheme is affected neither by the addition of ethylene glycol to the solution, nor by the presence of adsorbed polymer at the interface. Values for C obtained from analysis of the electrode impedance spectrum compare well with those obtained from potentiometric titrations of suspensions. For aqueous solutions Zw is identified as the Warburg impedance for semi-infinite linear diffusion of Ag+ or I− ions, although for I− the agreement between measured and calculated values is less than that for Ag+. In the presence of ethylene and the polymers PVA and PVP, C is reduced.In the presence of adsorbed polymers. Zw is increased, especially at relatively negative potentials. These results are discussed in terms of the structure of the interfacial double layer and the adsorbed polymer layer." @default.
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• W1543222145 date "1985-02-01" @default.
• W1543222145 modified "2023-09-23" @default.
• W1543222145 title "Electrodynamics of the AgI/solution interface" @default.
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• W1543222145 doi "https://doi.org/10.1016/0368-1874(85)85501-5" @default.
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