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- W1543614456 startingPage "95" @default.
- W1543614456 abstract "This chapter discusses the aspects of the coordination chemistry of organoantimony ligands and antimony ligands free of substituents without the inclusion of the other pnicogens. The ligand systems discussed include tertiary stibines, R3Sb and R2Sb, RSb or Sb units in different environments and with various coordination patterns. The majority of the complexes involve coordination on transition metals but complexes with main group (including Sb) acceptors are also discussed. General features of organoantimony ligands compared with their lighter congeners are related to the low stability of Sb–C or Sb–Sb bonds, to the relative weak Lewis basicity and to a larger tendency for higher coordination. Several comparative studies reveal a higher reactivity and flexibility of antimony ligand systems compared to analogous P or As compounds. However, the differences between related antimony and bismuth ligands appear to be considerably larger. Many tertiary stibines have donor properties similar to phosphines or arsines and they are easily coordinated witha large variety of metal complex fragments, whereas bismuthines are often weak donors. X-ray diffractometry is a very useful tool for the study of antimony ligands, including labile systems which are protected from rapid decomposition only in the sphere of complex." @default.
- W1543614456 created "2016-06-24" @default.
- W1543614456 creator A5030981947 @default.
- W1543614456 creator A5046067785 @default.
- W1543614456 date "2003-01-01" @default.
- W1543614456 modified "2023-10-12" @default.
- W1543614456 title "Ligands Coordination Compounds with Organoantimony and Sb Ligands" @default.
- W1543614456 cites W1486792230 @default.
- W1543614456 cites W1940504296 @default.
- W1543614456 cites W1964700751 @default.
- W1543614456 cites W1967550785 @default.
- W1543614456 cites W1971344771 @default.
- W1543614456 cites W1974022077 @default.
- W1543614456 cites W1975921328 @default.
- W1543614456 cites W1976166146 @default.
- W1543614456 cites W1981218925 @default.
- W1543614456 cites W1983091361 @default.
- W1543614456 cites W1987192174 @default.
- W1543614456 cites W1989991877 @default.
- W1543614456 cites W1991139059 @default.
- W1543614456 cites W1991497845 @default.
- W1543614456 cites W1993358685 @default.
- W1543614456 cites W1993795285 @default.
- W1543614456 cites W1994173518 @default.
- W1543614456 cites W1996608497 @default.
- W1543614456 cites W1997423149 @default.
- W1543614456 cites W1997574597 @default.
- W1543614456 cites W2000774450 @default.
- W1543614456 cites W2001153133 @default.
- W1543614456 cites W2002967935 @default.
- W1543614456 cites W2005604381 @default.
- W1543614456 cites W2006883778 @default.
- W1543614456 cites W2008490632 @default.
- W1543614456 cites W2009435976 @default.
- W1543614456 cites W2009813389 @default.
- W1543614456 cites W2009904062 @default.
- W1543614456 cites W2010299390 @default.
- W1543614456 cites W2010564078 @default.
- W1543614456 cites W2011732080 @default.
- W1543614456 cites W2012124640 @default.
- W1543614456 cites W2016170809 @default.
- W1543614456 cites W2016184864 @default.
- W1543614456 cites W2019340730 @default.
- W1543614456 cites W2023292829 @default.
- W1543614456 cites W2023512785 @default.
- W1543614456 cites W2024044691 @default.
- W1543614456 cites W2024354121 @default.
- W1543614456 cites W2024841954 @default.
- W1543614456 cites W2025841905 @default.
- W1543614456 cites W2027612562 @default.
- W1543614456 cites W2028486700 @default.
- W1543614456 cites W2031077094 @default.
- W1543614456 cites W2031454402 @default.
- W1543614456 cites W2038142790 @default.
- W1543614456 cites W2041777072 @default.
- W1543614456 cites W2045055425 @default.
- W1543614456 cites W2045331989 @default.
- W1543614456 cites W2057933436 @default.
- W1543614456 cites W2058279761 @default.
- W1543614456 cites W2058796357 @default.
- W1543614456 cites W2061439125 @default.
- W1543614456 cites W2061949733 @default.
- W1543614456 cites W2062840137 @default.
- W1543614456 cites W2063411676 @default.
- W1543614456 cites W2064535264 @default.
- W1543614456 cites W2065781351 @default.
- W1543614456 cites W2066062835 @default.
- W1543614456 cites W2066111603 @default.
- W1543614456 cites W2070674711 @default.
- W1543614456 cites W2072289673 @default.
- W1543614456 cites W2073116746 @default.
- W1543614456 cites W2073456741 @default.
- W1543614456 cites W2074174027 @default.
- W1543614456 cites W2074451271 @default.
- W1543614456 cites W2077753470 @default.
- W1543614456 cites W2078777952 @default.
- W1543614456 cites W2079378978 @default.
- W1543614456 cites W2079539077 @default.
- W1543614456 cites W2081981131 @default.
- W1543614456 cites W2082149464 @default.
- W1543614456 cites W2085349375 @default.
- W1543614456 cites W2090671801 @default.
- W1543614456 cites W2092332122 @default.
- W1543614456 cites W2092402335 @default.
- W1543614456 cites W2092715186 @default.
- W1543614456 cites W2092895903 @default.
- W1543614456 cites W2094419957 @default.
- W1543614456 cites W2097437154 @default.
- W1543614456 cites W2099956987 @default.
- W1543614456 cites W2105637841 @default.
- W1543614456 cites W2107950555 @default.
- W1543614456 cites W2112437563 @default.
- W1543614456 cites W2113123503 @default.
- W1543614456 cites W2117614133 @default.
- W1543614456 cites W2122849996 @default.
- W1543614456 cites W2128517019 @default.
- W1543614456 cites W2135865437 @default.
- W1543614456 cites W2143627405 @default.