Matches in SemOpenAlex for { <https://semopenalex.org/work/W1544285611> ?p ?o ?g. }
- W1544285611 endingPage "928" @default.
- W1544285611 startingPage "916" @default.
- W1544285611 abstract "The formation, their stability and the thermodynamic parameters of the binary complexation of Am3+, Cm3+ and Eu3+ with DTPA and of the ternary complexation of DTPA + IDA were studied in aqueous solutions of I = 6.60 m (NaClO4) and temperatures of 0–60 °C by solvent extraction technique. The stability constants of these complexes increased with increasing temperature. Positive enthalpy and the large entropy values for the binary and the ternary complexation indicated significant effect of cation dehydration at such high ionic strengths. TRLFS and NMR (1H and 13C) data provided insight into the structure of the ternary complexes in solution. In the binary [M(DTPA)]2− complex, M3+ binds via five carboxylates and three nitrogens, while in the ternary complex [M(DTPA)(IDA)]4−, DTPA binds by the same eight coordination sites and IDA binds via one of its carboxylate anion groups." @default.
- W1544285611 created "2016-06-24" @default.
- W1544285611 creator A5026077273 @default.
- W1544285611 creator A5052846911 @default.
- W1544285611 creator A5075471249 @default.
- W1544285611 date "2007-10-01" @default.
- W1544285611 modified "2023-09-26" @default.
- W1544285611 title "Thermodynamics and the structure of binary and ternary complexation of Am3+ Cm3+ and Eu3+ with DTPA and DTPA+IDA" @default.
- W1544285611 cites W1523730836 @default.
- W1544285611 cites W1580734443 @default.
- W1544285611 cites W1969593756 @default.
- W1544285611 cites W1970756979 @default.
- W1544285611 cites W1976201645 @default.
- W1544285611 cites W1983206722 @default.
- W1544285611 cites W1989292165 @default.
- W1544285611 cites W1990214725 @default.
- W1544285611 cites W1997496003 @default.
- W1544285611 cites W2003112316 @default.
- W1544285611 cites W2007937579 @default.
- W1544285611 cites W2009691828 @default.
- W1544285611 cites W2014445279 @default.
- W1544285611 cites W2014938377 @default.
- W1544285611 cites W2016633476 @default.
- W1544285611 cites W2021809316 @default.
- W1544285611 cites W2022224382 @default.
- W1544285611 cites W2037690147 @default.
- W1544285611 cites W2039398848 @default.
- W1544285611 cites W2040680632 @default.
- W1544285611 cites W2050320947 @default.
- W1544285611 cites W2054465568 @default.
- W1544285611 cites W2056186272 @default.
- W1544285611 cites W2059135111 @default.
- W1544285611 cites W2061357816 @default.
- W1544285611 cites W2063046153 @default.
- W1544285611 cites W2063777268 @default.
- W1544285611 cites W2069524005 @default.
- W1544285611 cites W2075238460 @default.
- W1544285611 cites W2106084782 @default.
- W1544285611 cites W2140503533 @default.
- W1544285611 cites W2140582014 @default.
- W1544285611 cites W2325662307 @default.
- W1544285611 cites W4245831818 @default.
- W1544285611 cites W4252278582 @default.
- W1544285611 doi "https://doi.org/10.1016/j.crci.2007.03.018" @default.
- W1544285611 hasPublicationYear "2007" @default.
- W1544285611 type Work @default.
- W1544285611 sameAs 1544285611 @default.
- W1544285611 citedByCount "8" @default.
- W1544285611 countsByYear W15442856112012 @default.
- W1544285611 countsByYear W15442856112013 @default.
- W1544285611 countsByYear W15442856112015 @default.
- W1544285611 countsByYear W15442856112016 @default.
- W1544285611 countsByYear W15442856112019 @default.
- W1544285611 countsByYear W15442856112020 @default.
- W1544285611 crossrefType "journal-article" @default.
- W1544285611 hasAuthorship W1544285611A5026077273 @default.
- W1544285611 hasAuthorship W1544285611A5052846911 @default.
- W1544285611 hasAuthorship W1544285611A5075471249 @default.
- W1544285611 hasConcept C121332964 @default.
- W1544285611 hasConcept C145148216 @default.
- W1544285611 hasConcept C147789679 @default.
- W1544285611 hasConcept C168191866 @default.
- W1544285611 hasConcept C178790620 @default.
- W1544285611 hasConcept C179104552 @default.
- W1544285611 hasConcept C181199279 @default.
- W1544285611 hasConcept C184651966 @default.
- W1544285611 hasConcept C185592680 @default.
- W1544285611 hasConcept C187428577 @default.
- W1544285611 hasConcept C199360897 @default.
- W1544285611 hasConcept C2182769 @default.
- W1544285611 hasConcept C2778074193 @default.
- W1544285611 hasConcept C3288061 @default.
- W1544285611 hasConcept C41008148 @default.
- W1544285611 hasConcept C64452783 @default.
- W1544285611 hasConcept C71240020 @default.
- W1544285611 hasConcept C8010536 @default.
- W1544285611 hasConcept C86756495 @default.
- W1544285611 hasConcept C97355855 @default.
- W1544285611 hasConceptScore W1544285611C121332964 @default.
- W1544285611 hasConceptScore W1544285611C145148216 @default.
- W1544285611 hasConceptScore W1544285611C147789679 @default.
- W1544285611 hasConceptScore W1544285611C168191866 @default.
- W1544285611 hasConceptScore W1544285611C178790620 @default.
- W1544285611 hasConceptScore W1544285611C179104552 @default.
- W1544285611 hasConceptScore W1544285611C181199279 @default.
- W1544285611 hasConceptScore W1544285611C184651966 @default.
- W1544285611 hasConceptScore W1544285611C185592680 @default.
- W1544285611 hasConceptScore W1544285611C187428577 @default.
- W1544285611 hasConceptScore W1544285611C199360897 @default.
- W1544285611 hasConceptScore W1544285611C2182769 @default.
- W1544285611 hasConceptScore W1544285611C2778074193 @default.
- W1544285611 hasConceptScore W1544285611C3288061 @default.
- W1544285611 hasConceptScore W1544285611C41008148 @default.
- W1544285611 hasConceptScore W1544285611C64452783 @default.
- W1544285611 hasConceptScore W1544285611C71240020 @default.
- W1544285611 hasConceptScore W1544285611C8010536 @default.
- W1544285611 hasConceptScore W1544285611C86756495 @default.
- W1544285611 hasConceptScore W1544285611C97355855 @default.