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- W1544338636 abstract "The synthesis of silicalite-2 (MEL structure) is reported in order to understand the effect, on chemico-physical properties, of some parameter modifications during the synthesis, such as silica source. MEL type zeolites with intergrowth with MFI-type structure were prepared and the percentage of the two phases has been changed. The effect of synthesis parameters on crystals shape and size was investigated. Silicalite-2 catalysts were tested in the vapour phase Beckmann rearrangement of cyclohexanone oxime. In some cases interesting results leading to long catalyst lifetime (over 80 hours) and interesting caprolactam selectivity (>90%) are obtained." @default.
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- W1544338636 date "2005-01-01" @default.
- W1544338636 modified "2023-10-16" @default.
- W1544338636 title "High-silica MEL structures: synthesis parameters modification and catalytic results on Beckmann rearrangement reaction" @default.
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- W1544338636 doi "https://doi.org/10.1016/s0167-2991(05)80539-7" @default.
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