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- W1544927534 abstract "The molecular ions of the title compounds appear to lose a benzyl radical, which must be due to the presence of two benzyloxy groups, as benzylalkyl ethers do not exhibit such an expulsion upon electron impact. The results of the partition of the labels deuterium and 18O in the ions m/e 107 (protonated benzaldehyde) and [M-benzyl-benzaldehyde]+ put forward evidence that this process is initiated by a successive migration of a benzylic H atom to the opposite ether function and transfer of the benzyl cation from this protonated O atom to the uncharged O atom in an SNi-type reaction (cf Scheme 5)." @default.
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- W1544927534 date "1974-01-01" @default.
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- W1544927534 title "On the loss of a benzyl radical from the molecular ion of α,ω -dibenzyloxyalkanes" @default.
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- W1544927534 doi "https://doi.org/10.1016/s0040-4020(01)97030-9" @default.
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