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- W1545364998 abstract "A modified Birch-Murnaghan equation of state, K l, 0 = (2/3)P [(Δ p /Δ0)7/5 − (Δ p /Δ0)]−1 is used to evaluate zero-pressure polyhedral bulk moduli, K l, 0, for transition metal-bearing coordination polyhedra from pressure-induced variations of the crystal field splitting parameter, Δ, obtained from visible-near infrared spectral measurements of oxides and silicates. The K l, 0 values generally agree with polyhedral bulk moduli derived from high-pressure X-ray data. The spectral method for evaluating polyhedral bulk moduli is best suited to cubic (isometric) phases containing transition metals in regular, or only slightly distorted, octahedral or cubic (8-fold) environments. Such coordination polyhedra occur in garnet, spinel, periclase, and perovskite structure-types in the mantle." @default.
- W1545364998 created "2016-06-24" @default.
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- W1545364998 date "1987-01-01" @default.
- W1545364998 modified "2023-10-10" @default.
- W1545364998 title "Polyhedral bulk moduli from high-pressure crystal field spectra" @default.
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- W1545364998 doi "https://doi.org/10.1029/gm039p0361" @default.
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