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- W1545608692 endingPage "1932" @default.
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- W1545608692 abstract "Coupled oxidation of protohaem with ascorbate and molecular oxygen was studied under conditions of low oxygen partial pressure. Reaction conditions were established whereby a reasonable extent of reaction was achieved without total depletion of the oxygen present. Under these conditions, experiments with 18,18O216,16O2 mixtures failed to reveal the presence of the isotopically scrambled species 18,16O2 following coupled oxidation. Under the same conditions, no H218,16O2 was detected in solution following reaction. These data suggest that a mechanism for haem degradation involving evolution of a dioxygen species cannot account for the experimental observation of a Two-Molecule Mechanism whereby the lactam O atoms in the product bile pigment are derived from each of two oxygen molecules. An alternative mechanism is proposed." @default.
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- W1545608692 date "1983-01-01" @default.
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- W1545608692 title "The mechanism of haem degradation" @default.
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- W1545608692 doi "https://doi.org/10.1016/s0040-4020(01)88707-x" @default.
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