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- W1546119241 abstract "Cyclobutene, prepared by base-induced elimination from tosyloxycyclobutane 19 undergoes cycloaddition with ethyl propiolate in the presence of AlCl3 to provide ethyl bicyclo[2.2.0]hex-2-ene-2-carboxylate 20. This cycloadduct at room temperature and in the presence of AlCl3 undergoes forbidden ring opening into ethyl cyclohexa-1,3-diene-2-carboxylate 21. The cycloaddition of cyclobutene with dichloroketene provides 3,3-dichlorobicyclo [2.2.0]hexan-2-one 24 and after reductive halogen removal the endo 3-chloro bicyclo[2.2.0]hexan-2-one 28 (the first study of this strained system). However, further dechlorination of 28 results in rearrangement and fragmentation reactions." @default.
- W1546119241 created "2016-06-24" @default.
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- W1546119241 date "1983-01-01" @default.
- W1546119241 modified "2023-10-09" @default.
- W1546119241 title "Small ring compounds—XLI" @default.
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- W1546119241 doi "https://doi.org/10.1016/s0040-4020(01)88564-1" @default.
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