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- W1546787401 abstract "The mechanism of propene-deuterium exchange reaction was investigated over alumina supported Os 3 (CO) 12 , Ir 4 (CO) 12 and Rh 4 (CO) 12 carbonyl cluster derived catalysts by applying a microwave spectroscopic technique. The coverage dependence of the preadsorbed CO upon the structure and the activity of the intermediates was studied in detail. A new reaction pathway was proposed in C 3 H 6 −C 3 D 6 reaction, which involves an intermolecular hydrogen shift between two adsorbed propene molecules." @default.
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- W1546787401 date "2000-01-01" @default.
- W1546787401 modified "2023-09-27" @default.
- W1546787401 title "Evolution of a new reaction pathway in propene-deuterium exchange reaction by the co-adsorption of CO over Rh, Ir, and Os carbonyl cluster derived catalysts supported on alumina" @default.
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- W1546787401 doi "https://doi.org/10.1016/s0167-2991(00)80820-4" @default.
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