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• W1547366314 abstract "Layered rare earth compounds in the RMn 2 X 2 series (R = rare‐earth; X = Ge, Si) are of interest for potential cooling applications at lower temperatures as they enable the structural and magnetic behavior to be controlled via substitution of R, Mn, and X atoms on the 2a, 4d, and 4e sites respectively. We continue investigations of the Pr 1− x Y x Mn 2 Ge 2 magnetic phase diagram as functions of both composition and Mn–Mn spacing using X‐ray and neutron diffraction, magnetization and differential scanning calorimetry measurements. Pr 1− x Y x Mn 2 Ge 2 exhibits an extended region of re‐entrant ferromagnetism around x ∼ 0.5 with re‐entrant ferromagnetism at for Pr 0.5 Y 0.5 Mn 2 Ge 2 . The entropy values −Δ S M around the ferromagnetic transition temperatures from the layered antiferromagnetic AF l structure to the canted ferromagnetic structure F mc (typically ) have been derived for Pr 1− x Y x Mn 2 Ge 2 with x = 0.0, 0.2, and 0.5 for Δ B = 0–5 T. The changes in magnetic states due to Y substitution for Pr are discussed in terms of chemical pressure, external pressure, and electronic effects." @default.
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• W1547366314 date "2014-03-26" @default.
• W1547366314 modified "2023-10-16" @default.
• W1547366314 title "Magnetic transitions and the magnetocaloric effect in the Pr_1−<i>x</i>Y_<i>x</i>Mn₂Ge₂system" @default.
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• W1547366314 doi "https://doi.org/10.1002/pssa.201330640" @default.
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