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- W1547388228 abstract "Colloidal lanthanide (Gd, Eu, Tb, Sm, Ce(III)) compounds consisting of particles of narrow size distribution were obtained by aging at elevated temperatures solutions of corresponding salts in the presence of urea. Cerium(III) yielded crystalline oxydicarbonate solids of ellipsoidal shape, while the other rare-earth elements produced sols of amorphous spherical particles of basic carbonates. The effects of various parameters (pH, temperature, nature of anions, aging time) on the properties of the resulting precipitates were studied systematically. The metal hydroxycarbonates were readily converted to the corresponding oxides, without a change in morphology, by calcination at 600°C. The size distribution, specific surface area, and weight loss on calcination, as well as optical, fluorescent, and electrokinetic properties of the precipitated solids were evaluated. An apparatus designed for continuous production of such sols is described." @default.
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- W1547388228 date "1987-08-01" @default.
- W1547388228 modified "2023-10-16" @default.
- W1547388228 title "Preparation and properties of monodispersed colloidal particles of lanthanide compounds" @default.
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- W1547388228 doi "https://doi.org/10.1016/0021-9797(87)90486-3" @default.
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