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• W1547530227 abstract "We report an electron spin resonance (ESR) study on a C60 anion and a metal (M) encapsulated in fullerene (Cn) (a metallofullerene: M@Cn). The anisotropy components of the g-factor of C60− were determined accurately from the analysis of angular-dependent ESR spectra of single crystal C60− salt. The evaluation of the g-factor was performed according to the classification of symmetry of the C60− geometry. It was found out from the evaluation that the molecular structure of C60− should be distorted to lower symmetry, C2h or Ci. The variety of ESR spectra of metallofullerenes of La@Cns was obtained in terms of a g-factor, a hyperfine coupling constant, and a line width. In the case of the isomer I of La@C80 and the isomer II of La@C84, an abnormally large line width was measured. The molecular structure with high symmetry would reflect on the specific spin dynamics." @default.
• W1547530227 created "2016-06-24" @default.
• W1547530227 creator A5064655602 @default.
• W1547530227 date "2003-01-01" @default.
• W1547530227 modified "2023-09-24" @default.
• W1547530227 title "Cage Structure Distortion of Fullerenes" @default.
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• W1547530227 doi "https://doi.org/10.1016/s0065-3276(03)44020-3" @default.
• W1547530227 hasPublicationYear "2003" @default.
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