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• W1547544218 abstract "Glass-forming Ti-based alloys are considered as potential new materials for implant applications. Ti75Zr10Si15 and Ti60Zr10Nb15Si15 alloys (free of cytotoxic elements) can be produced as melt-spun ribbons with glassy matrix and embedded single β-type nanocrystals. The corrosion and passivation behavior of these alloys in their homogenized melt-spun states have been investigated in Ringer solution at 37°C in comparison to their cast multiphase crystalline counterparts and to cp-Ti and β-type Ti-40Nb. All tested materials showed very low corrosion rates as expressed in corrosion current densities icorr < 50 nA/cm2. Electrochemical and surface analytical studies revealed a high stability of the new alloys passive states in a wide potential range. This corresponds to low passive current densities ipass = 2 ± 1 µA/cm2 based on the growth of oxide films with thickness d <10 nm. A homogeneous constituent distribution in the melt-spun alloys is beneficial for stable surface passivity. The addition of Nb does not only improve the glass-forming ability and the mechanical properties but also supports a high pitting resistance even at extreme anodic polarization up to 4V versus SCE were oxide thickness values of d ∼35 nm are reached. With regard to the corrosion properties, the Nb-containing nearly single-phase glassy alloy can compete with the β-type Ti-40Nb alloy. SBF tests confirmed the ability for formation of hydroxyapatite on the melt-spun alloy surfaces. All these properties recommend the new glass-forming alloys for application as wear- and corrosion-resistant coating materials for implants. © 2015 Wiley Periodicals, Inc. J Biomed Mater Res Part B: Appl Biomater, 104B: 27–38, 2016." @default.
• W1547544218 created "2016-06-24" @default.
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• W1547544218 date "2015-01-21" @default.
• W1547544218 modified "2023-09-29" @default.
• W1547544218 title "Designing new biocompatible glass-forming Ti_75- <i> _x </i> Zr₁₀ Nb<i> _x </i> Si₁₅ (<i>x</i> = 0, 15) alloys: corrosion, passivity, and apatite formation" @default.
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• W1547544218 doi "https://doi.org/10.1002/jbm.b.33332" @default.
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