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- W1548008045 abstract "Organized mesoporous silica (OMS) constitute new solids with many potential applications, particularly in the field of catalysis. These materials with very well organized pores can be obtained upon lowering the pH of highly basic sodium silicate solutions in the presence of cationic surfactants such as cetyltrimethylammonium bromide (CTAB) or chloride (CTAC). The first steps of formation (prior to precipitation) of these materials have been investigated by in situ probing fluorescence techniques. The results for the CTAB systems indicate that only a small fraction of micelle-bound bromide ions is exchange by hydroxyl and silicate ions. Moreover, the presence of these additives increases very little the micelle aggregation number in CTAB and CTAC-containing systems, indicating that there is hardly any micelle growth under the experimental conditions used." @default.
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- W1548008045 date "2001-01-01" @default.
- W1548008045 modified "2023-09-24" @default.
- W1548008045 title "On the mechanism of formation of organized mesoporous silica that may be used as catalysts for FCC" @default.
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- W1548008045 doi "https://doi.org/10.1016/s0167-2991(01)82328-4" @default.
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