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- W1548379691 abstract "Carbonate-rich periplatform sediments represent an active carbon reservoir containing metastable aragonite and magnesian calcite (Mg-calcite, > 4 mol % MgCO3). Since Mg-calcite is highly soluble, the preservation state of this mineral provides information on past carbonate systems at water depths shallower than the lysocline. The mineralogy and geochemistry of the carbonate-rich fine fraction (<63 μm) was determined for the last 940 ka in a sediment core collected from the Walton Basin (Northern Caribbean Sea, 846 m water depth). Mg/Ca ratios for Mg-calcite showed clear glacial-interglacial cycles with high values (12 mol % MgCO3) during interglacials. Glacial Mg/Ca ratios were approximately 8 mol % MgCO3 for the period from 940 ka to 400 ka, and approximately 10 mol % MgCO3 for the last 400 ka. The Mg/Ca shift is concomitant with a preferential loss of Mg-calcite relative to aragonite. The preservation state of Mg-calcite revealed that the bottom water mass of the studied site was slightly more corrosive for the earlier period, possibly relating to a composition change in intermediate water and/or to the ventilation rate in the Atlantic Ocean." @default.
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- W1548379691 date "2009-11-01" @default.
- W1548379691 modified "2023-10-10" @default.
- W1548379691 title "Preservation state of metastable magnesian calcite in periplatform sediments from the Caribbean Sea over the last million years" @default.
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- W1548379691 doi "https://doi.org/10.1029/2009gc002779" @default.
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