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- W1548380675 abstract "Microlatices of acrylic monomers, in the particle size range of 10–30 nm, were prepared by photopolymerization of micellar systems (monomer-surfactant) and of microemulsions based on monomer-surfactant-cosurfactant. Formation of monomer containing microemulsions is shown for various surfactants in combination with alcohols as cosurfactants and the corresponding phase diagrams are given. Photopolymerization, in the presence of oil-soluble initiators, was investigated for such systems based on cyclohexyl methacrylate (CHMA) and on tetramethylene dimethacrylate (BDMA). Crosslinked and non-crosslinked colloidal polymer particles could be obtained, with a 5–10% solid content of polymer. The variation of particle size, and the molecular weight for non-crosslinked systems, was studies as a function of initiator concentration, and monomer/surfactant ratio. The smallest particles (10–15 nm) are obtained for the system BDMA/lauryl sulfate (LS)." @default.
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- W1548380675 date "1989-04-01" @default.
- W1548380675 modified "2023-10-10" @default.
- W1548380675 doi "https://doi.org/10.1002/macp.1989.021900406" @default.
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