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- W1548638461 abstract "The kinetics of acrylonitrile polymerisation initiated by the redox system V(V)-ethylene glycol were investigated in aqueous sulfuric acid in the temperature range 40–50°C. The rate of polymerisation, of V(V) disappearance, and the chain lengths of polyacrylonitrile were measured. The effect of certain water miscible organic solvents and certain neutral salts on the rate of polymerisation was investigated. The kinetics are consistent with the formation of an intermediate complex between the diol and the oxidant whose decomposition leads to the initiating radical. A suitable kinetic scheme is proposed and the various rate and energy parameters are computed." @default.
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- W1548638461 date "1977-11-01" @default.
- W1548638461 modified "2023-09-26" @default.
- W1548638461 doi "https://doi.org/10.1002/macp.1977.021781101" @default.
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