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- W1549396959 abstract "Absorption spectra for O316 and O318 near 1 μ have been recorded to explore the rotational structure associated with the A23 and B23 electronic states of ozone. Rotational features within the A23←A11 1-0 band respond predictably to isotopic substitution, enabling determination of the upper state adiabatic electronic energy and asymmetric stretching frequency via isotope shift techniques. We find an adiabatic energy of 9963±4 cm−1, in excellent agreement with that determined earlier from vibronic isotope shifts observed at lower resolution, 9990±70 cm−1. We also find an asymmetric stretching frequency of 367±17 cm−1, indicating that the A23 state potential energy surface is bound against dissociation to O+O2 despite the fact that it lies above the corresponding dissociation limit. Rotational structure associated with transitions to the B23 state is detected for the first time. It responds anomalously to O18 substitution. The geometry of the upper state for O318 appears to differ markedly from that for O316 (Δθ≈−4 deg, or Δre≈+0.07A), suggesting that the B23 surface is strongly anharmonic and precluding a straightforward analysis of the isotope shifts." @default.
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- W1549396959 date "1998-04-01" @default.
- W1549396959 modified "2023-09-27" @default.
- W1549396959 title "Rotational structure in the absorption spectra of O318 and O316 near 1 μm: A comparative study of the A23 and B23 states" @default.
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- W1549396959 doi "https://doi.org/10.1063/1.475933" @default.
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