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- W1550202292 abstract "The reaction of molybdenum trioxide with gadolinium acetate produces an insoluble hydrated salt that converts to monoclinic Gd 2 (MoO 4 ) 3 upon heating to 800°C and then to ferroelectric orthorhombic Gd 2 (MoO 4 ) 3 after heating to 1000°C. A processible, water-soluble precursor for Gd 2 (MoO 4 ) 3 was obtained in a one-pot reaction of gadolinium carbonate, gluconic acid, and molybdenum trioxide. The product of this reaction contains MoO 2 2+ moieties that are complexed to two double deprotonated (at the carboxylate and 2-hydroxyl positions. The resulting dianions have hydrated gadolinium cations as counter ions. Heating this material to 640°C produces Gd 2 (MoO 4 ) 3 ." @default.
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- W1550202292 date "2012-04-25" @default.
- W1550202292 modified "2023-09-27" @default.
- W1550202292 title "Novel Routes to Ferroelectric Gadolinium Molybdenum Oxides" @default.
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- W1550202292 doi "https://doi.org/10.1002/9781118408162.ch4" @default.
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