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- W1550889490 abstract "Abstract The existence of vesicles composed of synthetic cationic surfactant, dioctadecyldimethylammonium chloride (DOAC) alone was confirmed by electron microscopy and was supported by 13 C- and 1 H-nmr spectroscopy. The single bilayer and multilamellar vesicles obtained by ultrasonication were found to resemble very closely the patterns of those composed of natural phospholipids and to be stable for at least 3 months, once formed. It was also found from the results of sonication time dependence of viscosity and electrical conductivity that the vesicle formation of DOAC was not easier than that of phospholipids. 1 H-nmr line widths of (CH 2 ) n and N + (CH 3 ) 2 protons in DOAC vesicle bilayers decreased with increasing temperature, but a discontinuous change in the linewidth (abrupt broadening) was observed at the transition temperature ( T c ) region (43–48°C). The result suggests that the hydration behavior of DOAC vesicles below T c is different from that above T c . The apparent activation energy for T 2 ∗ relaxation time obtained from the linewidth data was of the order of the potential barrier for the internal rotation of CC or CN bond." @default.
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- W1550889490 date "1978-06-01" @default.
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- W1550889490 title "Solution properties of long-chain dialkyldimethylammonium salts" @default.
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- W1550889490 doi "https://doi.org/10.1016/0021-9797(78)90267-9" @default.
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