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- W1550989855 abstract "Methyltrioxorhenium(VII) (MTO), known as an efficient olefin epoxidation catalyst, also catalyses the oxidation of metal carbonyls by hydrogen peroxide. Thus, treatment of the metal carbonyl precursor (η5-C5Me5)Re(CO)3 with H2O2 in the presence of catalytic amounts of MTO at temperatures ranging between −40 and 25°C gives trioxo(η5-pentamethylcyclopentadienyl)rhenium(VII) in almost quantitative isolated yield. Mild reaction conditions and high yields are the particular advantages of the new synthesis." @default.
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- W1550989855 date "1993-10-01" @default.
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- W1550989855 title "Mehrfachbindungen zwischen Hauptgruppenelementen und Übergangsmetallen" @default.
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- W1550989855 doi "https://doi.org/10.1016/0022-328x(93)86092-v" @default.
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