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- W1551110745 abstract "New solid solutions Cu 2 Mn x Fe 1− x SnS 4 were prepared by direct combination of the corresponding elements at 850 °C. The crystal structure of Cu 2 Mn 0.4 Fe 0.6 SnS 4 was determined by single‐crystal X‐ray diffraction. This phase is described in the space group where each cation is tetrahedrally coordinated to four sulfur anions in a sphalerite‐like arrangement. The XRD patterns of the solid solutions Cu 2 Mn x Fe 1− x SnS 4 were fully indexed in the space group and the values of the cell parameter for all phases obey the usual linear Vegard behavior. A progressive evolution of the magnetic moment in the paramagnetic state is observed when increasing the content of manganese. The negative values of the Curie–Weiss constant, θ , indicate an antiferromagnetic (AF) behavior with AF interactions, weaker by more than one order of magnitude compared to other diluted magnetic semiconductors (DMSs) with zinc‐blende or wurzite crystal structure." @default.
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- W1551110745 date "2014-01-29" @default.
- W1551110745 modified "2023-10-17" @default.
- W1551110745 title "Magnetic properties and crystal structure of solid-solution Cu2 Mn x Fe1−x SnS4 chalcogenides with stannite-type structure" @default.
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- W1551110745 doi "https://doi.org/10.1002/pssb.201350038" @default.
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