Matches in SemOpenAlex for { <https://semopenalex.org/work/W1551119153> ?p ?o ?g. }
- W1551119153 endingPage "2981" @default.
- W1551119153 startingPage "2975" @default.
- W1551119153 abstract "Die Barrieren der behinderten Rotation um die glycosidische Bindung (syn-anti-Isomerie) 6-substituierter Uracil-furanoside und verschiedener Lumazin-nucleoside werden aus der temperaturabhängigkeit der NMR-Spektren bestimmt. β-Riboside, α-2′-Desoxyriboside und ein α-Arabinosid zeigen ΔG+-Werte im Bereich 9–13 kcal/mol. in Fällen ist im Gleichgewicht bei −100°C die anti-Form vor dem syn-Rotameren etwas bevorzugt. Die syn-anti-Barriere wird auf der Basis einer sterischen Wechselwirkung zwischen Aglycon und Pentose diskutiert. Nucleosides, XII — Syn- and anti-isomeric Pentofurano-nucleosides The barriers to internal rotation around the glycosidic bond (syn-anti-isomerism) of 6-substituted uracil furanosides as well as several lumazine nucleosides were measured by variable temperature proton magnetic resonance. β-Ribosides, α-2′-deoxyribosides and an α-arabinoside all show ΔG+-values in the range of 9 to 13 kcal/mol. In all cases in thc equilibria around −100°C the anti-form predominates slightly over the syz-rotamer. The syn-anti-barrier is discussed in terms of steric interactions of aglycon and pentose." @default.
- W1551119153 created "2016-06-24" @default.
- W1551119153 creator A5006441776 @default.
- W1551119153 creator A5007447004 @default.
- W1551119153 creator A5028548622 @default.
- W1551119153 creator A5085302392 @default.
- W1551119153 creator A5090048895 @default.
- W1551119153 date "1973-09-01" @default.
- W1551119153 modified "2023-09-23" @default.
- W1551119153 title "Nucleoside, XII.Syn- undanti-isomere Pentofurano-nucleoside" @default.
- W1551119153 cites W1583162230 @default.
- W1551119153 cites W1584463377 @default.
- W1551119153 cites W1963698705 @default.
- W1551119153 cites W1967916013 @default.
- W1551119153 cites W1970190053 @default.
- W1551119153 cites W1970418530 @default.
- W1551119153 cites W1988980739 @default.
- W1551119153 cites W1994751679 @default.
- W1551119153 cites W1997721395 @default.
- W1551119153 cites W1999076339 @default.
- W1551119153 cites W1999811830 @default.
- W1551119153 cites W2002875598 @default.
- W1551119153 cites W2004299505 @default.
- W1551119153 cites W2011285501 @default.
- W1551119153 cites W2013713182 @default.
- W1551119153 cites W2017549918 @default.
- W1551119153 cites W2017966780 @default.
- W1551119153 cites W2025738476 @default.
- W1551119153 cites W2029287353 @default.
- W1551119153 cites W2037118705 @default.
- W1551119153 cites W2038842897 @default.
- W1551119153 cites W2046079355 @default.
- W1551119153 cites W2047531541 @default.
- W1551119153 cites W2048434956 @default.
- W1551119153 cites W2048905244 @default.
- W1551119153 cites W2052947365 @default.
- W1551119153 cites W2055089945 @default.
- W1551119153 cites W2058451118 @default.
- W1551119153 cites W2061822610 @default.
- W1551119153 cites W2062228040 @default.
- W1551119153 cites W2067358859 @default.
- W1551119153 cites W2070601711 @default.
- W1551119153 cites W2070849955 @default.
- W1551119153 cites W2072103671 @default.
- W1551119153 cites W2074210189 @default.
- W1551119153 cites W2076493734 @default.
- W1551119153 cites W2079840522 @default.
- W1551119153 cites W2080825199 @default.
- W1551119153 cites W2081664477 @default.
- W1551119153 cites W2086789134 @default.
- W1551119153 cites W2088563281 @default.
- W1551119153 cites W2124422238 @default.
- W1551119153 cites W2164664400 @default.
- W1551119153 cites W2164976851 @default.
- W1551119153 cites W2168704144 @default.
- W1551119153 cites W2329054760 @default.
- W1551119153 cites W2498633042 @default.
- W1551119153 cites W2902397868 @default.
- W1551119153 doi "https://doi.org/10.1002/cber.19731060928" @default.
- W1551119153 hasPublicationYear "1973" @default.
- W1551119153 type Work @default.
- W1551119153 sameAs 1551119153 @default.
- W1551119153 citedByCount "15" @default.
- W1551119153 crossrefType "journal-article" @default.
- W1551119153 hasAuthorship W1551119153A5006441776 @default.
- W1551119153 hasAuthorship W1551119153A5007447004 @default.
- W1551119153 hasAuthorship W1551119153A5028548622 @default.
- W1551119153 hasAuthorship W1551119153A5085302392 @default.
- W1551119153 hasAuthorship W1551119153A5090048895 @default.
- W1551119153 hasConcept C150487720 @default.
- W1551119153 hasConcept C178790620 @default.
- W1551119153 hasConcept C181199279 @default.
- W1551119153 hasConcept C185592680 @default.
- W1551119153 hasConcept C201194858 @default.
- W1551119153 hasConcept C2776543447 @default.
- W1551119153 hasConcept C2779554091 @default.
- W1551119153 hasConcept C552990157 @default.
- W1551119153 hasConcept C55493867 @default.
- W1551119153 hasConcept C71240020 @default.
- W1551119153 hasConceptScore W1551119153C150487720 @default.
- W1551119153 hasConceptScore W1551119153C178790620 @default.
- W1551119153 hasConceptScore W1551119153C181199279 @default.
- W1551119153 hasConceptScore W1551119153C185592680 @default.
- W1551119153 hasConceptScore W1551119153C201194858 @default.
- W1551119153 hasConceptScore W1551119153C2776543447 @default.
- W1551119153 hasConceptScore W1551119153C2779554091 @default.
- W1551119153 hasConceptScore W1551119153C552990157 @default.
- W1551119153 hasConceptScore W1551119153C55493867 @default.
- W1551119153 hasConceptScore W1551119153C71240020 @default.
- W1551119153 hasIssue "9" @default.
- W1551119153 hasLocation W15511191531 @default.
- W1551119153 hasOpenAccess W1551119153 @default.
- W1551119153 hasPrimaryLocation W15511191531 @default.
- W1551119153 hasRelatedWork W1551119153 @default.
- W1551119153 hasRelatedWork W1803328452 @default.
- W1551119153 hasRelatedWork W1987814593 @default.
- W1551119153 hasRelatedWork W1993673082 @default.
- W1551119153 hasRelatedWork W1994543348 @default.