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- W1551186281 abstract "Abstract Stable salts of the η 5 -cyclohexadienylphosphoniumruthenium(II) complexes [(η 5 -C 6 H 6 PR 3 )RuL 3 ] 2+ (PR 3 PMe 3 , PMe 2 Ph; L 3 (PMe 3 ) 3 , (PMe 3 ) 2 PPh 3 , (PMe 3 )(PPh 3 )PMe 2 Ph, (PMe 3 ) 2 P(NMe 2 ) 3 , (PMe 3 ) 2 MeCN) are obtained from [C 6 H 6 RuClL 2 ]PF 6 , C 6 H 6 RuCl 2 (L) or [C 6 H 6 Ru(MeCN) 3 ](PF 6 ) 2 and excess phosphine. At low temperature, both the 1 H and 31 P NMR spectra indicate a restricted rotation around the metal-to-ring bond. The reaction of [(η 5 -C 6 H 6 PR 3 RuL 3 ] 2+ with CF 3 COOH leads to elimination of the phosphonium-PR 3 group and formation of the dications [C 6 H 6 RuL 3 ] 2+ (L 3 (PMe 3 ) 3 , (PMe 3 ) 2 PPh 3 , (PMe 3 ) 2 MeCN)." @default.
- W1551186281 created "2016-06-24" @default.
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- W1551186281 date "1981-04-01" @default.
- W1551186281 modified "2023-09-27" @default.
- W1551186281 title "Untersuchungen zur reaktivität von metall-π-komplexen" @default.
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- W1551186281 doi "https://doi.org/10.1016/s0022-328x(00)86659-0" @default.
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