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- W1551251105 abstract "采用e-己内酯（CL）开环聚合的方法首先合成树枝状聚（醚-酰胺）基（DPEA）星形聚合物star-PCL,再与异氰酸基封端的PEG（PEG-NCO）偶合制备了两亲性树枝状聚（醚-酰胺）基星形嵌段聚合物star-PCL-b-PEG.利用FT-IR、^1H-NMR和GPC分析测试手段对star-PCL-b-PEG的结构进行了表征.通过滴加选择性溶剂的方法,制备了star-PCL-b-PEG以水为介质的类似“平头”聚集体胶束溶液.采用荧光光谱法测得star-PCL-b-PEG水溶液的临界胶束浓度（CMC）为1.623mg/L;采用激光光散射仪测得其在浓度0.15mg/mL和0.5mg/mL的流体力学半径分别为86.2nm和224.6nm,其多分散指数分别为0.115和0.197.透射电镜（TEM）观察发现胶束的形貌受共溶剂的特性,初始聚合物浓度,水含量等因素的影响." @default.
- W1551251105 created "2016-06-24" @default.
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- W1551251105 date "2008-09-15" @default.
- W1551251105 modified "2023-10-14" @default.
- W1551251105 title "PREPARATION AND MORPHOLOGIES OF MICELLE-LIKE AGGREGATES BASED ON DENDRITIC POLY(ETHER-AMIDE)" @default.
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- W1551251105 doi "https://doi.org/10.3724/sp.j.1105.2008.00609" @default.
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