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- W1551315369 abstract "Abstract The facile synthesis of three new folding azobenzene‐pyrene systems 1 – 3 , connected together by a serendipitously obtained and unpredicted ester linkage, is reported. Additional characterization of the photochemistry of these systems revealed variations in azobenzene photoisomerization ( trans‐cis and cis‐trans ) and quenching of pyrene fluorescence, as a result of intra‐excitation energy transfer from the pyrene chromophore to an azobenzene. Through the use of aryl substituent electronic effects to tune the absorption properties of the azobenzene relative to the pyrene, we show that efficient photo‐switching can be achieved when the trans ‐azobenzene absorbance band is well separated from that of the pyrene (compound 1 ), whereas overlap of the corresponding absorbance bands in the cases of 2 and 3 significantly compromises trans‐cis isomerization by enhancing cis‐trans interconversion." @default.
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- W1551315369 date "2013-12-05" @default.
- W1551315369 modified "2023-10-12" @default.
- W1551315369 title "Pyrene-Azobenzene Dyads and Their Photochemistry" @default.
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- W1551315369 doi "https://doi.org/10.1002/ejoc.201301301" @default.
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