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- W155153295 abstract "The ability of biomembrane lipids to undergo phase transformations into non-bilayer states, or into a variety of crystalline and gel phases, is a wellknown phenomenon. It is thought to be involved in various cellular events such as fusion, cell permeability, biomembrane damage, etc. Since, in many cases, these events are strongly influenced by the composition of the aqueous phase, it is of interest to develop a thermodynamic description of the stability of the lipid phases in aqueous solutions of low-molecular solutes. To this end, we consider a model thermodynamic system ~, consisting of an aggregate of NI lipid molecules together with N w molecules of bound water and N c solute molecules. The system ~, is kept at mechanical and thermal equilibrium at pressure p and temperature T, and in material contact with a reservoir R of water and solute molecules, the chemical potentials of which are/t w and/2¢, respectively. In order to simplify the arguments, we neglect the lipid solvability and assume that N I remains constant. The state of ~. is completely described by one extensive quantity, the number of lipid molecules N~, and four intensive variables: pressure p, temperature T, and chemical potentials/~w,/2~. Its thermodynamic potential is" @default.
- W155153295 created "2016-06-24" @default.
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- W155153295 date "2008-02-02" @default.
- W155153295 modified "2023-09-27" @default.
- W155153295 title "Thermodynamic stability of lipid phases in low-molecular solutions" @default.
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- W155153295 doi "https://doi.org/10.1007/bfb0118494" @default.
- W155153295 hasPublicationYear "2008" @default.
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