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• W1551646013 abstract "The crystal structure of (C6H5)3SnCH2C(CH3)CH2 has been determined. The asymmetric unit consists of two molecules of 2-methylallyltriphenyltin. The compound crystallizes in the orthorhombic space group Pbca with a 31.232(12). b 20.890(9), and c 11.835(7) Å. The molecular geometry is controlled by σ(CSn)-π orbital mixing and by hyperconjugative stablization involving the σ orbitals of CH bonds. Any pπdσ bonding between the metal and the allyl double bond, or inductive effects in the allyl group are shown to be unimportant. The structural parameters are analyzed and compared with those of various methylated derivatives of triphenyllalyltin." @default.
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• W1551646013 date "1989-05-01" @default.
• W1551646013 modified "2023-10-14" @default.
• W1551646013 title "Allyl- and allyllike-tin derivatives" @default.
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• W1551646013 doi "https://doi.org/10.1016/0022-328x(89)87249-3" @default.
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