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- W1551816156 abstract "Abstract The transparent disc electrode has been used to investigate three possible photogalvanic systems — the iron-thionine system and two iron-ruthenium systems. Results have been obtained for the photocurrent both in the steady state and for the modulated photocurrent produced when the light source is modulated. In the latter case the phase shift and amplitude of the photocurrent are measured as a function of the frequency of modulation. The results are in good agreement with the theoretical equation devised for the transparent rotating disc electrode, and the values of the rate constants obtained agree with those obtained by more conventional techniques such as stopped flow or flash photolysis. Moreover values are obtained for the overall quantum efficiency, φ, for the production of the electroactive species. For the ruthenium systems φ∼-1 but for the iron thionine system φ⋍0.8." @default.
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- W1551816156 date "1980-02-01" @default.
- W1551816156 modified "2023-10-06" @default.
- W1551816156 title "Photogalvanic cells" @default.
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- W1551816156 doi "https://doi.org/10.1016/s0022-0728(79)80003-0" @default.
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