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- W1552097796 abstract "Laser-induced Photoacoustic Spectroscopy (LPAS) is a new elegant instrumentation for the chemical speciation of aquatic transuranium (TRU) ions in very dilute concentrations (> 10−8 mol L−1). The aim of this paper is to review the application of LPAS to the study of the chemical behaviour of TRU ions in natural aquatic systems, the knowledge of which has become increasingly in demand in connection with the safety analysis of nuclear waste disposal in the geosphere. The first part of the paper describes the principle, instrumentation and characteristics of LPAS in aqueous solution, taking particular examples from our own experience. The theoretical estimation of the speciation sensitivity is demonstrated and the result is compared with experiment. The second part deals with the spectral work in aqueous solution and then with the application of LPAS for the speciation of TRU ions in groundwater. Some examples demonstrated are hydrolysis reaction, complexation and colloid generation of the Am3+ ion. Speciation sensitivities of U, Np, Pu and Am of different oxidation states in a variety of aqueous solutions are summarized. The present review is so oriented that the expected readers will appreciate the introductory understanding of the LPAS method and its potential applicability in the aquatic chemistry of TRU ions. The application is of course open to a broad field of microchemistry in which the conventional spectrophotometric method has difficulty with sensitivity." @default.
- W1552097796 created "2016-06-24" @default.
- W1552097796 creator A5055018817 @default.
- W1552097796 creator A5087793629 @default.
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- W1552097796 date "1990-01-01" @default.
- W1552097796 modified "2023-10-03" @default.
- W1552097796 title "Laser-induced photoacoustic spectroscopy for the speciation of transuranic elements in natural aquatic systems" @default.
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- W1552097796 doi "https://doi.org/10.1007/3-540-52423-1_5" @default.
- W1552097796 hasPublicationYear "1990" @default.
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