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- W1552313405 abstract "Multiphoton ionization (MPI) mass spectra of n-C3H7I and i-C3H7I are obtained using a time-of-flight mass spectrometer at 532 nm. No parent ions are observed in MPI of both isomers. N-propyl cation dissociates more extensively than isopropyl cation. The C2H5+ (M/Z = 29) ion is observed instead of C2H4+ (M/Z = 28) ion in MPI of n-C3H7I, in contrast to i-C3H7I. It is found that parent molecules are first two-photon resonantly excited to A-band, then go through dissociation. Fragment ions are produced by ionization and dissociation of neutral fragments. We present directly the dissociation pathways of n-propyl cation according to the results proposed by Levine using maximum entropy formalism. Moreover, those of isopropyl cation are discussed in this paper through branching ratio analyses." @default.
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- W1552313405 date "1998-04-01" @default.
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- W1552313405 title "Multiphoton ionization mass spectra of n-C 3 H 7 I and i-C 3 H 7 I at 532 nm" @default.
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- W1552313405 doi "https://doi.org/10.1088/1004-423x/7/4/004" @default.
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