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- W1552437487 abstract "The electrode reactions of the Eu(II)/Eu(Hg) system in aqueous and mixed H2O + DMF solutions of different supporting electrolytes (TEAP, LiClO4, Ca(ClO4)2) have been investigated by single potential step chronocoulometry and dc polarography. It was found that both reduction of Eu(II) and oxidation of Eu amalgam in the presence of acidified 0.05 mol dm−3 Ca(ClO4)2 are simple processes controlled both by diffusion and electrochemical kinetics in the whole range of DMF concentration (0–100%). The kinetic data obtained are discussed according to the models of electrochemical kinetics in mixed solvents proposed earlier. It was shown that the difference between the activation energies for pure aqueous and DMF solutions is concordant with that expected for the electron transfer mechanism with transfer of the second electron as the rate determining step." @default.
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- W1552437487 date "1985-10-01" @default.
- W1552437487 modified "2023-10-17" @default.
- W1552437487 title "Electrode reactions at extremely negative potentials" @default.
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- W1552437487 doi "https://doi.org/10.1016/0022-0728(85)85061-0" @default.
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