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- W1552676880 abstract "Synthetic studies towards(he C(3)-C(13)and C(14)-C(24)segments(3,4)of the potent antiviral and antitumor compound macrolactin A(1)are presented.Compound 3 was constructed via a convergent and facile approach,exploiting Wittig olefination to generate the sensitive E,Z-diene moiety.Compound 4 was synthesized from the chiral-pod derived sul-fone 39a via an o-alkylation-desulfonation reaction sequence.Cu(Ⅱ)-catalyzed coupling of a Grignard reagent with an al-lylic bromide and Julia olefination were also investigated for the preparation of compound 4." @default.
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- W1552676880 date "2000-01-01" @default.
- W1552676880 modified "2023-09-23" @default.
- W1552676880 title "A stereoselective synthesis of the C(3)-C(13) and C(14)-C(24) fragments of macrolactin A" @default.
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