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- W1552697274 abstract "The use of quinone compounds as potentiometric indicators for acidity measurements in anhydrous hydrogen fluoride (AHF) is described. The correct response of such indicators to pF variations and their stability in very acidic media were verified. A comparison is made with the hydrogen electrode which suffers from some drawbacks in AHF; the interest of the quinone acidity indicators in thus pointed out. Acid-base titrations are performed with various acidic and basic solutes and the corresponding titration curves are determined by means of quinonic indicators and a glassy carbon electrode. Values of the basicity constants of the considered solutes are deduced from these titration curves and discussed together with the value (10−11.5) of the ionic product of AHF. An acidity scale is established in this solvent: no strong acid appears to exist; even antimony pentafluoride cannot be considered as a strongly acidic compound." @default.
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- W1552697274 date "1975-09-01" @default.
- W1552697274 modified "2023-10-01" @default.
- W1552697274 title "Use of quinone systems as electrochemical pH indicators in anhydrous hydrogen fluoride solvent" @default.
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- W1552697274 doi "https://doi.org/10.1016/s0022-0728(75)80016-7" @default.
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