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- W1552794948 abstract "The yields of isopropyl alcohol and propyl alcohol in the reactions of PrX (X = Br, I) under the influence of the aquo ions of T1(III), Hg(II), Cd(II), and Ag(I) were determined in aqueous solutions of electrolytes (HClO/sub 4/, Mg(ClO/sub 4/)/sub 2/) which reduce the thermodynamic activity of the water and increase the degree of isomerization during the hydrolysis of primary alkyl halides. On the basis of the obtained relationship between the degree of isomerization and the nature of the M/sup z+/ cation it was concluded that the metal ions give rise to rearrangement mainly because they increase the positive charge at the ..cap alpha..-carbon atom in CH/sub 3/CH/sub 2/CH/sub 2//sup +/X/sup -/M/sup z+/ and change the state of the water near R/sup +/ in the ion triplet." @default.
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- W1552794948 date "1986-04-10" @default.
- W1552794948 modified "2023-09-23" @default.
- W1552794948 title "Isomerization in the ion triplet Pr/sup +/X/sup -/M/sup z+/ - an intermediate in the hydrolysis of PrX - with electrophilic assistance from metal ions" @default.
- W1552794948 hasPublicationYear "1986" @default.
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