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- W1552923296 abstract "The solution structure of filipin III, an antifungal polyene macrolide biosynthesized by Streptomyces filipinensis and widely used for the detection and the quantitation of cholesterol in biomembranes, has been calculated with a set of geometrical restraints derived from 1H NMR in DMSO-d(6) at 25 degrees C. Filipin III appears as a rod-shaped molecule of 18 A length. Its amphiphilic structure is made of an all-syn 1,3-polyol motif, stabilized by intramolecular hydrogen bonds on one side, and a conjugated pentaene moiety on the other side of the molecule. The overall shape is comparable to cholesterol, and the molecular structure of filipin III affords a first molecular basis to the comprehensive understanding of the interactions possible in the filipin III-cholesterol complex which is still unknown at the atomic resolution." @default.
- W1552923296 created "2016-06-24" @default.
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- W1552923296 date "2000-07-24" @default.
- W1552923296 modified "2023-09-25" @default.
- W1552923296 title "Solution NMR structures of the polyene macrolide antibiotic filipin III" @default.
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- W1552923296 doi "https://doi.org/10.1016/s0014-5793(00)01824-x" @default.
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