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- W155321888 abstract "Abstract The binary oxide TiO2-ZrO2, whose chemical and physical properties were found to be strongly dependent on metal oxide ratio, precipitation methodology and calcination temperature, was investigated as a support material for a CoO-MoO3 hydrodesulfurization (HDS) catalyst. Thiophene HDS studies at 1 atm and 300°C revealed that the TiO2-ZrO2 supported catalyst had an initial activity, on a weight basis, over twice that of a CoO-MoO3/Al2O3 catalyst, but suffered rapid deactivation. Nitric oxide chemisorption/temperature programmed desorption (TPD) results suggest that the high initial activity of the TiO2-ZrO2 supported catalyst may be due to a we ker Mo-support interaction, yielding a greater number of more reactive coordinatively unsaturated Mo sites. Thermal gravimetric analysis and differential scanning calorimetry results suggest that deactivation of the TiO2-ZrO2 supported catalyst is at least in part due to coke formation." @default.
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- W155321888 date "1988-01-01" @default.
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- W155321888 title "Hydrodesulfurization Over A TiO2-ZrO2 Supported Coo-MoO3 Catalyst: Effect of Metal-Support Interaction" @default.
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- W155321888 doi "https://doi.org/10.1016/s0167-2991(09)60686-8" @default.
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