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- W1553636789 abstract "3-Deoxy-2,5,6-tri- O -methyl- D - erythro -hex-2-enofuranose ( 4 ) was prepared by the action of lime-water on 2,3,5,6-tetra- O -methyl- D -glucofuranose ( 3 ). The α- D ( 6 ) and β- D ( 7 ) anomers of the methyl glycosides of 4 were obtained by methylation, and each was converted by methanolic acid into their anomeric mixture, and then into methyl 3-deoxy-5,6-di- O -methyl-α- and -β- D - erythro -hexofuranosidulose dimethyl acetal ( 8 and 9 ). The 5-( D -glycero-1,2-dimethoxyethyl)-3(2 H )-furanone ( 5 ) was formed by the action of aqueous acid on 4 and 6 – 9 . Preparative methods for 3 and for its methyl glycosides were improved." @default.
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- W1553636789 date "1966-10-01" @default.
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- W1553636789 title "Degradation of carbohydrates" @default.
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- W1553636789 doi "https://doi.org/10.1016/s0008-6215(00)81749-8" @default.
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