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- W1553668733 abstract "Photodissociation of bromine on the Br2(1Piu) state is probed with ultrafast extreme ultraviolet (53.7 nm) single-photon ionization. Time-resolved photoelectron spectra show simultaneously the depletion of ground state bromine molecules as well as the rise of Br(2P3/2) products due to 402.5 nm photolysis. A partial photoionization cross-section ratio of atomic versus molecular bromine is obtained. Transient photoelectron spectra of a dissociative wave packet on the excited state are presented in the limit of low-power-density, single-photon excitation to the dissociative state. Transient binding energy shifts of atomic-like photoelectron peaks are observed and interpreted as photoionization of nearly separated Br atom pairs on the Br2(1Piu) state to repulsive dissociative ionization states." @default.
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- W1553668733 date "2007-11-14" @default.
- W1553668733 modified "2023-09-26" @default.
- W1553668733 title "Transient photoelectron spectroscopy of the dissociative Br2(Πu1) state" @default.
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- W1553668733 doi "https://doi.org/10.1063/1.2803923" @default.
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