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- W1553730659 abstract "Abstract An assessment of the use of statistical atomic models for the study of many-electron atom confinement is presented. The Thomas–Fermi–Dirac- λ -Weizsacker TFDλW functional formalism based on known properties of the orbital electron density is shown to be an appropriate tool for the description of the ground-state energy evolution of many-electron atoms spatially limited by closed and open boundaries. A brief review of the strategy followed in the TFDλW method for the study of atoms enclosed in hard and soft spherical cavities is presented along with more refined quantitative calculations as compared with previous results. Also, detailed quantitative results are shown–for the first time–in the case of confinement by a hard prolate spheroidal box for nuclear positions located at one of the foci and for an atom located at a distance D from a hard plane. A discussion is presented on the physical consequences of different confinement geometries and the adequacy of the TFDλW formalism to explore many-electron atom confinement by open and closed boundaries." @default.
- W1553730659 created "2016-06-24" @default.
- W1553730659 creator A5060254072 @default.
- W1553730659 date "2009-01-01" @default.
- W1553730659 modified "2023-09-25" @default.
- W1553730659 title "Thomas–Fermi–Dirac–Weizsäcker Density Functional Formalism Applied to the Study of Many-electron Atom Confinement by Open and Closed Boundaries" @default.
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- W1553730659 doi "https://doi.org/10.1016/s0065-3276(09)00612-1" @default.
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