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- W1553758508 abstract "Superconducting Ca3Rh4Sn13 was quenched from high temperatures. X-ray diffraction measurements gave an indication of the type of defects (Sn atoms on the Ca sublattice) generated at high temperatures that are responsible for the degradation of the superconducting transition temperature. The relative degradation turns out to be about 10% for each per cent of anti-site Sn atoms on the Ca sublattice. Restoration of the superconducting transition temperature by annealing at intermediate temperatures is employed to study the kinetics of the defects. Values are obtained for the vacancy formation energy (1.10 eV) and the vacancy migration energy (0.89 eV). The activation energy for the annealing of anti-site defects is measured as 2.14 eV ( approximately=1.10 eV+0.89 eV), which suggests a vacancy mechanism for diffusion. The pre-exponential factor in the relaxation time for vacancy migration is obtained as 1.3*10-3 s and that for annihilation of anti-site atoms as 9.3*10-10 s." @default.
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- W1553758508 date "1989-08-21" @default.
- W1553758508 modified "2023-09-27" @default.
- W1553758508 title "Atomic disorder and superconductivity in Ca<sub>3</sub>Rh<sub>4</sub>Sn<sub>13</sub>" @default.
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- W1553758508 doi "https://doi.org/10.1088/0953-8984/1/33/012" @default.
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