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- W1554064095 abstract "A zeolite is a crystalline aluminosilicate with a three-dimensional framework structure that forms uniformly sized pores of molecular dimensions. As the pores preferentially adsorb molecules that fit snugly inside the pores and exclude molecules that are too large, they act as sieves on a molecular scale. Thus, zeolites are a subset of molecular sieves. They consist of robust, crystalline silica (SiO2) frameworks. At some places in the framework, AI3+ has replaced Si4+ and the framework carries a negative charge. Loosely held cations that sit within the cavities preserve the electro neutrality of the zeolite. Some of those cations are amenable to cation exchange and are able to reversibly interact with polar molecules. These properties have contributed significantly to the commercial success of zeolites. The use of molecular sieves with three-dimensional framework structures is well entrenched in areas as diverse as laundry detergents, oil refining and petrochemical industries, adsorbents, gas separations, agriculture and horticulture. Ever since the successful introduction of aluminosilicate molecular sieves (zeolites) in the late nineteen fifties, zeolites and the more recently discovered (silico) aluminophosphate molecular sieves have continuously improved current application areas and generated new ones." @default.
- W1554064095 created "2016-06-24" @default.
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- W1554064095 date "2001-01-01" @default.
- W1554064095 modified "2023-10-08" @default.
- W1554064095 title "Chapter 1 The zeolite scene—An overview" @default.
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- W1554064095 doi "https://doi.org/10.1016/s0167-2991(01)80242-1" @default.
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