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- W1554332810 abstract "Steady shear viscosities were measured over a range of shear rates from lower to upper-Newtonian flow region for solutions of polystyrene in the high-viscosity solvent tricresyl phosphate at three different temperatures. The influence of solvent viscosity on the non-Newtonian flow property was studied and compared with the results obtained previously by use of a lowviscosity solvent with similar solvent power for polystyrene as tricresyl phosphate. For the moderately concentrated solutions, the non-Newtonian viscosity could be explained by Graessley's entanglement viscosity theory modified by a frictional viscosity. The result shows that only the frictional viscosity is affected by variation of solvent viscosity. As the entanglement viscosity decreases with increasing shear rate and is practically masked by the shear independent frictional viscosity, the flow appears as to be upper-Newtonian in spite of the difference in solvent viscosity. The lower critical concentration for entanglement was determined on the basis of a lower limit for the applicability of the modified Graessley theory. The values of the critical concentrations are independent of the magnitude of solvent viscosities." @default.
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- W1554332810 date "1980-02-01" @default.
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- W1554332810 doi "https://doi.org/10.1002/macp.1980.021810210" @default.
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