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- W1554708054 abstract "Orthorhombic perovskite-type Ca(Mn1−xNbx)O3 exhibits a metal–insulator transition in the range 0.05⩽x⩽0.15. The spin-state of the Mn3+ ion does not change at the metal–insulator transition temperature (Tt). From the Rietveld analysis of Ca(Mn0.95Nb0.05)O3 at low temperature, the (Mn, Nb)–O(1)–(Mn, Nb) angle is independent of the temperature below Tt, and increases slightly above Tt. The metal–insulator transition is explained by the variation in the crystal structure and a release of the trapped electrons to the Mn–O–Mn matrix." @default.
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- W1554708054 date "2001-09-01" @default.
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- W1554708054 title "Metal–insulator transition in orthorhombic perovskite-type Ca(Mn1−xNbx)O3" @default.
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- W1554708054 doi "https://doi.org/10.1016/s0921-4526(01)00338-6" @default.
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